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丙烯酰胺接枝氰乙基淀粉增干强剂的制备及其对纸张的增强作用
引用本文:费贵强,沈一丁,王海花,李小瑞,李翾.丙烯酰胺接枝氰乙基淀粉增干强剂的制备及其对纸张的增强作用[J].中华纸业,2010,31(14):37-40.
作者姓名:费贵强  沈一丁  王海花  李小瑞  李翾
作者单位:教育部轻化工助剂化学与技术重点实验室,陕西科技大学,西安,710021
基金项目:国家自然科学基金项目,陕西省自然科学基金项目,陕西科技大学科研启动项目 
摘    要:碱性介质中,以木薯淀粉和丙烯腈为原料,制备了氰乙基淀粉,并以氰乙基淀粉为基础制备了丙烯酰胺接枝氰乙基淀粉反应性增干强剂,讨论了合成条件,并优化了合成工艺。实验结果表明:当m(丙烯腈)/m(淀粉)=0.3,w(DMC)=15%,w(AM)=50%,w(NAM)=3%,w(KPS)=0.6%,增干强剂用量在0.4%左右时,纸张环压强度和抗张强度分别提高37.8%和42.1%。

关 键 词:氰乙基淀粉  丙烯酰胺  接枝  增干强剂

Preparation and application of acrylamide grafted cyanoethyl starch as paper dry strengthening agent
FEI Gui-qiang,SHEN Yi-ding,WANG Hai-hua,LI Xiao-rui,LI Xuan.Preparation and application of acrylamide grafted cyanoethyl starch as paper dry strengthening agent[J].China Pulp & Paper Industry,2010,31(14):37-40.
Authors:FEI Gui-qiang  SHEN Yi-ding  WANG Hai-hua  LI Xiao-rui  LI Xuan
Affiliation:(Key Laboratory of Additives Chemistry & Technology for Light Chemical Industry, Ministry of Education, Shaanxi University of Science & Technology, Xi’an 710021, China)
Abstract:Cyanoethyl starch was prepared by reacting cassava starch with acrylonitrile in alkaline medium, and then the acrylamide grafted cyanoethyl starch as a dry strengthening agent for paper was therefore prepared with it as raw material. Factors influencing synthetic conditions were discussed, and synthetic procedure was simultaneously optimized. The results show that paper is endowed with excellent strength performance when m(AN)/m(starch)=0.3, w(DMC)=15%, w(AM)=50%, w(NAM)=3%, w(KPS)=0.6% and the dosage of dry strength agent is 0.3%. Under such circumstances, the tensile strength and ring crush strength of paper are increased by 37.8% and 42.1% respectively.
Keywords:cyanoethyl starch  acrylamide  graft  dry strengthening agent
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