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Generation of platinum microstructures on non-conducting surfaces by means of the scanning electrochemical microscope (SECM)
Authors:Valentin Radtke,Christian Heß  ,Jü  rgen Heinze
Affiliation:a Institut für Physikalische Chemie, Albertstr. 21, Albert-Ludwigs-Universität Freiburg, D-79104 Freiburg, Germany
b Freiburger Materialforschungszentrum (FMF), Stefan-Meier-Straße 21, Albert-Ludwigs-Universität Freiburg, D-79104 Freiburg, Germany
Abstract:The scanning electrochemical microscope (SECM) was used to form platinum microstructures. For this purpose, a thin layer of platinum dichloride was deposited as precursor on different substrates by evaporating it in high vacuum. For the reduction of this precursor the SECM provided methyl viologen radical cations locally as reducing agent. The mechanism of the reduction is discussed.
Keywords:Electroless metal deposition   Scanning electrochemical microscopy   SECM   Platinum generation   Microelectrode   Micropatterning   Chronoamperometry
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