Thermodynamic properties and defect structure of semiconducting compound phases: Tin telluride |
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Authors: | Jen-Chwen Lin T Leo Ngai Y Austin Chang |
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Affiliation: | (1) Department of Metallurgical and Mineral Engineering, University of Wisconsin-Madison, 1509 University Avenue, 53706 Madison, WI |
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Abstract: | Defect equilibria for binary semiconducting compound phases which exhibit ionized native donor and acceptor defects were considered,
and equations describing the pressure-temperature-composition relationships for these compound phases were derived. These
equations were used to analyze experimental data from the literature for tin telluride. Excellent agreement was obtained between
calculated thermodynamic and phase boundary values and experimental data. The approach presented is readily extended to obtain
equations for the thermodynamic properties of ternary and higher order semiconducting compound phases. |
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