Ion—solvent interaction: viscosity of ternary electrolytes in dioxane-water mixtures at 35° |
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Authors: | PB Das |
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Affiliation: | Department of Chemistry, S.C.S. College, Puri, India |
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Abstract: | The viscosities of the chlorides, bromides and nitrates and perchlorates of Mg2+ and Ba2+, of the chlorides and nitrates of Ca2+ and Sr2+, and of the sulphates of Na+ and K+ at mass fraction of dioxane, 10, 20 and 30% have been measured at 35°. The values of the constant A and B of the viscosity equation indicate ion—ion and ion—solvent interaction respectively. The ion-solvent interaction is found to be of the order NO?3 > ClO?4 > Br? > Cl? and K+ > Na+. |
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