| 2-(5-甲基-1,3,4-噁二唑-2-基)-6-二乙氨基荧烷的合成 |
| |
| 引用本文： | 戈乔华,项斌,高建荣,沈卫庆,程水良. 2-(5-甲基-1,3,4-噁二唑-2-基)-6-二乙氨基荧烷的合成[J]. 浙江工业大学学报, 2006, 34(5): 498-501 |
| |
| 作者姓名： | 戈乔华 项斌 高建荣 沈卫庆 程水良 |
| |
| 作者单位： | 浙江工业大学,绿色化学合成技术国家重点实验室培育基地,浙江,杭州,310032 |
| |
| 摘 要： | 以间氨基苯酚为原料经烷基化和Friedel—Crafts酰基化反应生成了2-羧基-4-二乙基氨基-2-羟基二苯甲酮．以对甲氧基苯甲酸为原料经酯化，肼化和环合成反应合成了2-甲基-5-对甲氧基苯基噁二唑．再用2-羧基-4-二乙基氨基-2-羟基二苯甲酮和2-甲基-5-对甲氧基苯基噁二唑经环合反应合成了2-（5-甲基-1，3，4-噁二唑-2-基）-6-二乙氨基荧烷．产物经^1H NMR，IR，元素分析等检测确定．
|
| 关 键 词： | 荧烷 噁二唑 染料 二苯甲酮 功能色素 |
| 文章编号： | 1006-4303(2006)05-0498-04 |
| 收稿时间： | 2006-01-12 |
| 修稿时间： | 2006-01-12 |
Synthesis of 2- (5-methyl-1, 3,4-oxadiazole-2-yl) -6-diethylaminofluoran |
| |
| GE Qiao-hua,XIANG Bin,GAO Jian-rong,SHEN Wei-qing,CHENG Shui-liang. Synthesis of 2- (5-methyl-1, 3,4-oxadiazole-2-yl) -6-diethylaminofluoran[J]. Journal of Zhejiang University of Technology, 2006, 34(5): 498-501 |
| |
| Authors: | GE Qiao-hua XIANG Bin GAO Jian-rong SHEN Wei-qing CHENG Shui-liang |
| |
| Affiliation: | Zhejiang University of Technology, State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology Hangzhou 310032, China |
| |
| Abstract: | The 2-Carboxyl-4'-diethylamino-2'-hydroxybenzophenone was obtained via alkylation and Friedel-Crafts acylation reaction using 3-diethylaminophenol as the raw material.The 5-Methyl-2-(4-methoxyphenyl)-1,3,4-oxadiazole was synthesized by means of esterification,hydraziding and cyclization using p-methoxybenzoic acid.The 2-(5-Methyl-1,3,4- oxadiazole -2-yl)-6-diethylaminofluoran was prepared from 2-carboxyl -4'-diethylamino -2'-hydroxybenzophenone and 5-methyl-2-(4-methoxyphenyl)-1,3,4-oxadiazole.These compounds were identified by IR,~1H NMR,UV and element analysis. |
| |
| Keywords: | fluoran oxadiazole dye benzophenone functional pigments |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
