Coke deposition and run length in industrial naphtha thermal cracking furnaces via a quasi-steady state coupled CFD model |
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Authors: | Mohsen Rezaeimanesh S. Ali Asghar Ghoreyshi Seyed Mohsen Peyghambarzadeh Seyed Hassan Hashemabadi |
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Affiliation: | 1. Chemical Engineering Department, Babol Noshirvani University of Technology, Babol, Iran;2. Department of Chemical Engineering, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran;3. Computational Fluid Dynamics Research Laboratory, School of Chemical Engineering, Iran University of Science and Technology, Tehran, Iran |
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Abstract: | Mathematical modelling of the thickness of the coke layer growing over months in millisecond cracking reactors is a dilemma in computational fluid dynamics (CFD) simulation. To address the time scale issue, a quasi-steady state (QSS) approach was employed through a comprehensive coupled reactor/firebox CFD model in the current study. The model was applied to predict the time-dependent behaviour of coke deposition and to determine the appropriate operating conditions for maximum olefin yields over an industrial furnace run length. A novel algorithm was designed to overcome the complexity of QSS simulation of the CFD model, which is a combination of reactive turbulence flow, combustion, and radiation models. The furnace parameters were studied as a function of two variables: the dilution steam-to-feed ratio and the liberated heat by the burners. The results indicated that the run length can be extended by up to 20% while retaining the main product yields. This study offers practical suggestions to maximize the run length in the operation. |
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Keywords: | coil outlet temperature coke thickness radiant coil skin temperature |
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