Cu-ZSM5 as reusable catalyst for the one-pot,odorless and ligand-free C-S bond formation |
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| Affiliation: | 1. Department of Chemistry, Faculty of Science, University of Kurdistan, Zip Code, 66177-15175, Sanandaj, Iran;2. Research Centre of Nanotechnology, University of Kurdistan, P.O. Box 416, Sanandaj, Iran |
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| Abstract: | CuI-ZSM5 and CuII-ZSM5 as reusable and heterogeneous nanocatalysts were synthesized and characterized using various techniques. The catalysts have been applied for the practical synthesis of various phenyl aryl/benzyl sulfides via one-pot and odorless processes from the reaction of triphenyltin chloride or phenylboronic acid as phenyl source with different aryl/benzyl halides in the presence of S8 as sulfur source and KF or KOH as S8 activator in DMF at 80 °C. |
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