Enhancing kinetics of biodiesel production using morpholine
Affiliation:
1. Department of Applied Chemistry, Faculty of Engineering, Kyushu Institute of Technology, 1-1 Sensuicho, Tobata, Kitakyushu 804-8550, Japan;2. Graduate School of Life Science and Systems Engineering, Kyushu Institute of Technology, 2-4 Hibikino, Wakamatsu-ku, Kitakyushu 808-0196, Japan;3. Research Center for Eco-fitting Technology, Kyushu Institute of Technology, 2-4 Hibikino, Wakamatsu-ku, Kitakyushu 808-0196, Japan;1. Department of Thoracic Surgery, Liaoning Provincial Tumor Hospital, Shenyang 110042, China;2. Department of Medical Oncology, Liaoning Provincial Tumor Hospital, Shenyang 110042, China
Abstract:
This work illustrates morpholine assisted transesterification of crude canola oil, corn oil and coffee oil (extracted from spent coffee grounds) using NaOH as a homogeneous base catalyst. Addition of morpholine resulted in a two-fold enhancement in kinetics of transesterification. The properties of the biodiesel final product were evaluated by fuel standard tests and the results were compared with ASTM D6751 standards. Biodiesel produced from canola, coffee and corn oils was found to have a high cetane number (52.5–55.1) and good flash point (140 °C).