Controlling conditions for synthesis of iron-titanium carbide using two different titanium precursors |
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| Affiliation: | 1. Pyrometallurgy Lab., Minerals Technology Dep., Central Metallurgical R&D Institute (CMRDI), P.O Box 87, Cairo, Egypt;2. Chemistry Dep., Faculty of Science, Zagazig University, Zagazig, Egypt;1. College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics & Astronautics, Nanjing 210016, China;2. College of Physics and Electronic Engineering, Zhejiang Provincial Key Laboratory for Cutting Tools, Taizhou University, Taizhou 318000, China;1. Department of Materials Science and Engineering, National Cheng Kung University, Tainan 701, Taiwan;2. Department of Materials Engineering, Kun Shan University, Tainan 710, Taiwan;3. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, PR China;4. Interdisciplinary School of Green Energy and Low Dimensional Carbon Materials Center, Ulsan National Institute of Science and Technology (UNIST), UNIST-gil 50, Ulsan 689-798, Republic of Korea;5. Department of Mechanical Engineering, National Chin-Yi University of Technology, Taiping City, Taichung County 411, Taiwan;6. Center for Micro/Nano Science and Technology, National Cheng Kung University, Tainan 701, Taiwan;7. Research Center for Energy Technology and Strategy, National Cheng Kung University, Tainan 701, Taiwan;8. Department of Chemical and Materials Engineering, National University of Kaohsiung, Kaohsiung 811, Taiwan;1. School of Engineering and Technology, China University of Geosciences (Beijing), Beijing 100083, China;2. Key Laboratory on Deep Geo-drilling Technology of the Ministry of Land and Resources, China University of Geosciences (Beijing), Beijing 100083, China |
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| Abstract: | Preparation of Fe–TiC composite from mixtures of carbon black and two different titanium bearing minerals (black sand ilmenite and natural rutile) was studied. Milled (mechanically activated) and unmilled carbon containing mixtures were prepared and then heated at temperatures 1200 °C and 1300 °C for 3 h under an inert atmosphere. The reaction progress, as well as reaction products, was evaluated using thermogravimetric analysis (TGA-DTA), X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and energy dispersive X-ray spectroscopy (EDX). The feasibility of producing Fe–TiC composites from titanium bearing materials mixed with carbon black was proved. Fe–TiC could be produced by carbothermic reduction of mechanically activated black sand ilmenite containing mixtures milled for 50 h and heated up to 1200 °C. On the other hand, 60 h milling followed by heating up to 1300 °C was needed in case of natural rutile containing mixture. The morphology of the Fe–TiC produced from black sand ilmenite showed a homogeneous distribution of Fe and TiC enriched areas, while the Fe–TiC produced from natural rutile showed intense distribution of TiC phase with traces of iron and lower titanium oxide. |
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