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A consideration of circulating bed electrodes for the recovery of metal from dilute solutions
Authors:K. Scott
Affiliation:(1) Department of Chemical Engineering, Teesside Polytechnic, Borough Road, Middlesbrough, Cleveland, UK
Abstract:A comparison is made of three types of circulating particulate electrodes: spouted (circulating) bed (SBE), vortex bed (VBE) and moving bed (MBE). In applications such as metal recovery, all electrodes perform similarly in terms of current efficiency. On the basis of scale-up, it appears that the spouted bed electrode is the preferred system.Nomenclature I cell current (A) - F Faraday constant (94487 C mol–1) - C dimensionless concentration - CF friction factor - C0 Initial concentration (mol m–3) - D pipe equivalent diameter (m) - eb bed voidage - ec voidage of conveying section - L bed length (m) - Sb cross section area of bed (m2) - ST cross section area of conveying section (m2) - T dimensionless time=It/nFVC0 - Uf superficial liquid velocity in conveying (m s–1) - Ui particle terminal velocity corrected for wall effects (m s–1) - Us particle velocity in transport (m s–1) - USL slip velocity (m s–1) - t time (s) - V electrolyte volume (m3) - Vf liquid velocity in the bed (m s–1) - Vmf minimum fluidization velocity (m s–1) - Vs particle velocity in the bed (m s–1) - DeltaP pressure drop (NM–2) - rhov fluid density (kg m–3) - rhovs particle density (kg m–3) - Re Reynolds number
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