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Synthesis of cyclic carbonates from carbon dioxide and epoxides using alkali metal halide supported liquid phase catalyst
Authors:Sachin R Jagtap  Mayur J Bhanushali  Anil G Panda  Bhalchandra M Bhanage
Affiliation:(1) Surface and Catalysis Research Centre, School of Chemistry, University of Reading, Whiteknights, Reading, RG6 6AD, UK
Abstract:Using combination of Mn–Co transition metal species with N-hydroxyphthalimide as a catalyst for one-step oxidation of cyclohexane with molecular oxygen in acetic acid at 353 K can give more than 95% selectivity towards oxygenated products with adipic acid as a major product at a high conversion (ca. 78%). A turnover number of 74 for this partial oxidation are also recorded.
Keywords:adipic acid  one-step oxidation  catalyst  cyclohexane oxidation            N-hydroxyphthalimide  radical  selectivity
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