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氟苯废液资源化处理工艺研究
引用本文:李安云,董庆华,费正皓.氟苯废液资源化处理工艺研究[J].应用化工,2007,36(4):330-333.
作者姓名:李安云  董庆华  费正皓
作者单位:1. 盐城师范学院,化学化工学院江苏省滩涂生物资源与环境保护重点建设实验室,江苏,盐城,224002;盐城市盐都区环境监测站,江苏,盐城,224008
2. 盐城师范学院,化学化工学院江苏省滩涂生物资源与环境保护重点建设实验室,江苏,盐城,224002
基金项目:江苏省科技厅科研项目;江苏省教育厅资助项目;江苏省重点实验室基金
摘    要:氟苯生产过程中产生的废硫酸和废水混合,经隔油、冷却沉淀处理,COD从134.5 g/L降到12.0 g/L,COD去除率91%,酚含量从19 g/L降到3.7 g/L;混合液再经树脂吸附处理,COD平均值在1 g/L左右,COD去除率约92%,苯酚未检出;树脂采用10%氢氧化钠溶液脱附,效果良好,对COD的脱附率达98.5%以上。

关 键 词:氟苯  废硫酸  含酚废水  树脂吸附  资源化
文章编号:1671-3206(2007)04-0330-04
修稿时间:2007-01-12

Treatment of wastewater from producing fluorobenzene
LI An-yun,DONG Qing-hua,FEI Zheng-hao.Treatment of wastewater from producing fluorobenzene[J].Applied chemical industry,2007,36(4):330-333.
Authors:LI An-yun  DONG Qing-hua  FEI Zheng-hao
Abstract:In this paper,the wastewater containing sulfuric acid from producing fluorobenzene was treated and the treating procedure and method including of mixing,removing oil,pretreatment and adsorption was proposed.After treatment with above procedure,the removal efficiency of chemical oxygen demand(COD) in waste solution reaches 91% from 134.5 g/L to 12 g/L,and the concentration of phenol decreases from 19 g/L to 3.7 g/L.And through next adsorbing onto resin,the removal efficiency of COD in waste solution reaches about 92% to 1 g/L without phenol.The desorption efficiency is about 98.5% with 10% NaOH as desorption solvent.
Keywords:fluorobenzene  waste sulfuric acid  wastewater containing phenol  adsorption with resin  reuse
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