| 含邻氨基苯甲酸新型三核席夫碱化合物的合成与表征 |
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| 引用本文： | 袁泽利,玉孪,吴庆,江艳,杨武,胡庆红,张铭钦. 含邻氨基苯甲酸新型三核席夫碱化合物的合成与表征[J]. 化学世界, 2009, 50(6) |
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| 作者姓名： | 袁泽利 玉孪 吴庆 江艳 杨武 胡庆红 张铭钦 |
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| 作者单位： | 遵义医学院药学系,贵州,遵义,563003 |
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| 摘 要： | 以邻氨基苯甲酸、3-羧基水杨醛、乙酸铜和乙酸锌为原料合成了新型Cu2+、Zn2+三核席夫碱配合物。以氯仿和无水乙醇做溶剂,在pH7~8的条件下顺利合成得到了新型Cu2+、Zn2+三核席夫碱配合物,并对它们的合成条件分别进行了探索性实验,确定了合成它们的各自优化条件。产品通过元素分析1、H NMRI、R、UV和MS进行组成和结构表征。
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| 关 键 词： | 邻氨基苯甲酸 席夫碱 合成 表征 |
Synthesis and Characterization of Novel Polynuclear Schiff Base Compounds Containing o-Aminobenzoic Acid |
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| YUAN Ze-li,YU Luan,WU Qing,JIANG Yan,YANG Wu,HU Qing-hong,ZHANG Ming-qin. Synthesis and Characterization of Novel Polynuclear Schiff Base Compounds Containing o-Aminobenzoic Acid[J]. Chemical World, 2009, 50(6) |
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| Authors: | YUAN Ze-li YU Luan WU Qing JIANG Yan YANG Wu HU Qing-hong ZHANG Ming-qin |
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| Affiliation: | Department of Pharmacy;Zunyi Medical College;Guizhou Zunyi 563003;China |
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| Abstract: | The novel polynuclear Schiff base compounds containing o-aminobenzoic acid were synthesized from o-aminobenzoic acid,3-carboxylsalicylaldeyde,cupper(Ⅱ) acetate or zinc(Ⅱ) acetate.The reaction was carried out in the solution with pH from 7 to 8,and the solvents were anhydrous ethanol and CHCl_3.The favorable conditions of synthesizing the novel polynuclear Schiff base compounds were found after a series of experiments,and the Schiff bases were characterized by elemental analysis,~1H NMR,IR,UV and MS. |
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| Keywords: | o-aminobenzoic acid Schiff base synthesis characterization |
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