首页 | 本学科首页   官方微博 | 高级检索  
     

二酰胺萃取钇、镧和铕的研究
引用本文:陈文浚,文永安,樊勤.二酰胺萃取钇、镧和铕的研究[J].核化学与放射化学,1999,21(3):136-141.
作者姓名:陈文浚  文永安  樊勤
作者单位:四川大学化学系!成都610064
基金项目:核科学基金,中国工程物理研究院院外基金
摘    要:以N,N'-二甲基-N,N'-二辛基-3-氧-戊二酰胺作萃取剂、适当有机溶剂作稀释剂时,在不加大伴阴离子的条件下,研究了水相硝酸浓度、盐析剂、有机相萃取剂浓度对钇、镧和铕萃取分配比的影响,并对其萃取机理进行了初步探讨。

关 键 词:二酰胺  萃取  稀土
修稿时间:1998-09-08

INVESTIGATION ON THE EXTRACTION OF Y~(3 ) ,Eu~(3 ) and La~(3 ) WITH DIAMIDE FROM NITRIC ACID SOLUTIONS
Chen Wenjun,Wen Yong''an,Fan qin.INVESTIGATION ON THE EXTRACTION OF Y~(3 ) ,Eu~(3 ) and La~(3 ) WITH DIAMIDE FROM NITRIC ACID SOLUTIONS[J].Journal of Nuclear and Radiochemistry,1999,21(3):136-141.
Authors:Chen Wenjun  Wen Yong'an  Fan qin
Abstract:Using suitable organic solvents as diluent,Y 3 ,Eu 3 and La 3 can be extracted effectively by N,N' dimethyl N,N' dioctyl 3 oxy glutaramide without large anion from nitric acid solutions.The effects of the concentration of the nitric acid,salt agents and Eu 3 in aqueous phase,and the extractant in organic phase on distribution ratioes are researched.The extractive mechanism is examined.The extractablity and selectivety of this extractant for trivalent rare earth ions are better than those of pentaalkylpropane diamides.
Keywords:Diamide  Extraction  Rare earth
本文献已被 CNKI 维普 万方数据 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号