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化学氧化聚合制备微/纳米结构聚苯胺研究进展
引用本文:李瑜,郑建龙,井新利.化学氧化聚合制备微/纳米结构聚苯胺研究进展[J].化工新型材料,2009,37(11).
作者姓名:李瑜  郑建龙  井新利
作者单位:1. 西安交通大学能源与动力工程学院化学工程系,西安,710049
2. 中国人民解放军总后勤部建筑工程研究所,西安,710049
摘    要:近年来多种见诸报道的新颖聚苯胺(PANI)微/纳米结构及其制备途径,可大体归为:主要控制了苯胺化学氧化聚合中聚合产物成核、生长过程或对聚合反应施加了影响.主要从聚合产物的生长和团聚、苯胺化学氧化聚合所用氧化剂和掺杂剂三方面归纳了制备微/纳米结构PANI的反应条件及其影响因素.

关 键 词:聚苯胺  纳米结构  无模板合成  氧化剂  掺杂剂

Development of preparation of polyaniline micro/nano structures through chemical oxidative polymerization
Li Yu,Zheng Jianlong,Jing Xinli.Development of preparation of polyaniline micro/nano structures through chemical oxidative polymerization[J].New Chemical Materials,2009,37(11).
Authors:Li Yu  Zheng Jianlong  Jing Xinli
Abstract:Various approaches to the synthesis of many novel polyaniline micro/nano structures reported in recent years can be considered as making efforts to control the nucleation and agglomeration of the polymerization products or af-fect the polymerization reaction itself. The present paper summarized the factors which influence the formation of polyani-line micro/nano structures from three aspects, i.e. growth and agglomeration of the polymerization products, the oxidants to initiate the aniline chemical oxidation polymerization and the dopants existing during polymerization.
Keywords:polyaniline  nanostructure  template-free synthesis  oxidant  dopant
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