| CO/CO2催化加氢双功能催化剂新进展 |
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| 引用本文： | 高新华,王康洲,张建利,马清祥,范素兵,赵天生. CO/CO2催化加氢双功能催化剂新进展[J]. 石油学报(石油加工), 2019, 35(6): 1228-1238. DOI: 10.3969/j.issn.1001-8719.2019.06.024 |
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| 作者姓名： | 高新华 王康洲 张建利 马清祥 范素兵 赵天生 |
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| 作者单位： | 宁夏大学 省部共建煤炭高效利用与绿色化工国家重点实验室 化学化工学院，宁夏 银川 750021 |
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| 基金项目： | 宁夏重点研发计划(东西部合作)项目(2017BY063)、宁夏自然科学基金项目(2018AAC02002)和宁夏化学工程与技术国内一流学科项目(NXYLXK2017A04)资助 |
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| 摘 要： | CO/CO2催化加氢制高附加值化学品是降低石油资源依赖、实现碳减排的有效途径。近年来国内外科学家致力于开发新型双功能催化剂，将传统F-T合成催化剂或甲醇合成催化剂分别与H-ZSM-5、SAPO-34等酸性分子筛耦合，实现了CO/CO2催化加氢一步制低碳烯烃、汽油、芳烃等化学品。围绕耦合不同反应，设计高效双功能催化剂，调控产物分布是碳一资源化学利用的关键。综述了“氧化物-分子筛”双功能催化剂发展近况，不同活性组分组合方式、空间距离对CO/CO2选择转化制高附加值化学品反应性能的影响，展望了双功能催化剂发展方向。
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| 关 键 词： | 双功能催化剂 催化加氢 一氧化碳(CO) 二氧化碳(CO2) 耦合反应 |
| 收稿时间： | 2018-10-10 |
Recent Advances in Bifunctional Catalysts for Hydrogenation of CO and CO2 |
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| GAO Xinhua,WANG Kangzhou,ZHANG Jianli,MA Qingxiang,FAN Subing,ZHAO Tiansheng. Recent Advances in Bifunctional Catalysts for Hydrogenation of CO and CO2[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2019, 35(6): 1228-1238. DOI: 10.3969/j.issn.1001-8719.2019.06.024 |
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| Authors: | GAO Xinhua WANG Kangzhou ZHANG Jianli MA Qingxiang FAN Subing ZHAO Tiansheng |
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| Affiliation: | State Key Laboratory of High Efficiency Utilization of Coal and Green Chemical Engineering, College of Chemistry & Chemical Engineering, Ningxia University, Yinchuan 750021, China |
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| Abstract: | The hydrogenation of CO and CO2 to highly value added hydrocarbons is one of the most fascinating strategies for the utilization of carbon resource and environment protection. The development of highly efficient bifunctional catalyst for CO and CO2 hydrogenation is still a huge challenge. Recently, many groups have successfully prepared bifunctional catalysts for the selective transformation of CO and CO2 to lower olefins, gasoline, aromatics, and so on. This review presents an overview of recent advances in CO and CO2 catalytic hydrogenation, in terms of bifunctional catalyst design, integration manner and the proximity effect of the active components. Finally, the article offers some perspectives on future research. |
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| Keywords: | bifunctional catalysts catalytic hydrogenation carbon monoxide carbon dioxide coupling reaction |
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