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Fabrication and magneto-optical property of yttria stabilized Tb2O3 transparent ceramics
Affiliation:1. Institute of Problems of Chemical Physics of RAS, 142432, Chernogolovka, Moscow Region, Russia;2. Institute of Chemistry of Tajik Academy of Science, Ajni Str. 299/2, 734063 Dushanbe, Tajikistan;3. Institute of Structural Macrokinetics and Materials Science of RAS, 142432, Chernogolovka, Moscow Region, Russia;4. Institute of Microelectronics Technology and High-Purity Materials of RAS, 142432, Chernogolovka, Moscow Region, Russia;5. National University of Science and Technology MIS&S, Leninsky pr. 4, 119049, Moscow, Russia;1. School of Materials Science and Engineering, Shanghai Institute of Technology, Shanghai 200235, China;2. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 200235, China;3. Department of Electronics and Information Materials, Shanghai University, Shanghai 200072, China;1. School of Materials Science and Engineering, Shaanxi University of Science & Technology, Xi''an 710021, China;2. Glass Coatings and Concepts LLC, Monroe, OH 45050, United States;3. College of Engineering and Applied Science, University of Cincinnati, Cincinnati, OH 45221, United States;1. G.G. Devyatykh Institute of Chemistry of High-Purity Substances RAS, Nizhny Novgorod, Russia;2. Institute of Applied Physics of the Russian Academy of Sciences, Nizhny Novgorod, Russia;1. Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang, 315211, China;2. Key Laboratory of Photoelectric Materials and Devices of Zhejiang Province, Ningbo, Zhejiang, 315211, China;3. Research Center for Functional Materials, National Institute for Materials Science, Tsukuba, Ibaraki, 305-0044, Japan;1. Key Laboratory of Transparent Opto-functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;2. University of Chinese Academy of Sciences, Beijing 100049, China;3. Department of Physics, Shanghai Normal University, Shanghai 200234, China
Abstract:(Tb0.5Y0.5)2O3 transparent ceramics have been prepared by wet chemical co-precipitation route and flowing H2 atmosphere sintering. The optical quality, microstructure and magneto-optical properties of the ceramics were investigated. No sintering aids or milling were adopted in the ceramic fabrication processing. The cold isostatic pressed green compact could be sintered to be transparent (Tb0.5Y0.5)2O3 ceramic at 1800 ℃ in flowing H2 atmosphere. The mechanical polished ceramic showed the good transmittance from visible to near infrared wavelength, corresponding to a 71.9% transmittance at 1400 nm wavelength. The Verdet constant measured at 632.8 nm of the (Tb0.5Y0.5)2O3 transparent ceramics was -220.19 rad T?1 m-1, which was 1.64 times that of Tb3Ga5O12 single crystal.
Keywords:Transparent ceramics  Magneto-optical property
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