| 水溶性烯土卟啉咯合物的合成及电化学行为研究 |
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| 引用本文： | 庄乾坤,高小霞.水溶性烯土卟啉咯合物的合成及电化学行为研究[J].辽宁石油化工大学学报,1996(3). |
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| 作者姓名： | 庄乾坤 高小霞 |
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| 作者单位： | 北京大学化学系 |
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| 摘 要： | 对水溶性镧系烯土－卟啉咯合物的合成、结构及其电化学特性进行了系统研究，讨论了其稳定性，测定了络合物的稳定常数，提出并讨论了烯土卟啉络合物的电极反应机理。
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| 关 键 词： | 烯土 卟啉 水溶性烯土卟啉 电极反应机理 |
The Synthesis and Electrochemical Study of the Watersoluble Lanthanide Porphyrins |
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| Zhuang Qiankun,Gao Xiaoxia.The Synthesis and Electrochemical Study of the Watersoluble Lanthanide Porphyrins[J].Journal of Liaoning University of Petroleum & Chemical Technology,1996(3). |
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| Authors: | Zhuang Qiankun Gao Xiaoxia |
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| Abstract: | We synthesized and characterized the water-soluble tetra-p-sulfonatophenylporphyrinatolanthanide, Ln·TPPS·OH·2im]. 3H 2O.Their stability and complex constants are also studied and determined. The structural formula of the lanthanide porphyrins is proposed, too. The lanthanide atom is sitting above the porphyrin plane. The electrode reaction mechanism of the lanthanide porphyrin complex at mercury electrode in ammoniacal(pH=9.35), phosphate(pH=7.0) and acetate(pH=4.95) buffer solutions is also studied. |
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| Keywords: | Lanthanide Porphyrin Water-soluble lanthanide porphyrin Electrode reaction mechanism |
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