Affiliation: | 1. Nanomaterials and Systems for Renewable Energy Laboratory, Research and Technology Center of Energy, Hammam Lif, Tunisia;2. Nanomaterials and Systems for Renewable Energy Laboratory, Research and Technology Center of Energy, Hammam Lif, Tunisia
Materials Science Institute of Madrid (ICMM), CSIC, c/Sor Juana Inés de la Cruz 3, Cantoblanco, Madrid, Spain;3. Materials Science Institute of Madrid (ICMM), CSIC, c/Sor Juana Inés de la Cruz 3, Cantoblanco, Madrid, Spain;4. Department of Chemistry, College of Science Al-Zulfi, Majmaah University, Al-Majmaah, Saudi Arabia;5. Departamento de Química Física Aplicada, Universidad Autónoma de Madrid, Madrid, Spain |
Abstract: | Sulfonated poly(ether ether ketone) (SPEEK) with a low sulfonation degree was blended using nanofiller layered double hydroxide (LDH, Mg2AlCl)/sepiolite nanostructured material as additive to use as an electrolyte membrane for fuel cell application. Characterization assessments, that is, mechanical stability, thermal gravimetric analysis, ion exchange capability, swelling properties, water uptake capacities, electrochemical impedance spectroscopy analysis, and Fourier transform infrared spectroscopy of the composite membranes were conducted. The presence of LDH/sepiolite nanoarchitectured material within SPEEK was found to have the highest water retention and proton conductivity value at high temperature rather than LDH/SPEEK and pristine SPEEK membranes. |