A comparative study on the influences of whisker and conventional carbon nanotubes on the electrical and thermal conductivity of polyether ether ketone composites |
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Authors: | Shu Li Fengyu Wen Cong Sun Zhenyang Wang Rui Chen Qingxia He Jianxin Mu |
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Affiliation: | 1. College of Chemistry, Engineering Research Center of High Performance Plastics, Ministry of Education, Jilin University, Changchun, China;2. Gas Chromatography-Mass Spectrometry Laboratory, Central Laboratory of Changchun Water [Group] Co., Ltd, Changchun, China |
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Abstract: | In this study, the electrical and thermal conductivity of polyether ether ketone (PEEK)/carbon nanotubes (CNTs) with different types, namely whisker CNTs (Wh-CNTs) and conventional CNTs were compared. PEEK/CNTs composites were melt mixed in PEEK via two screw extrusion technology. Moreover, the effects of different methods for mixing of PEEK/Wh-CNTs, namely, dry mixing, wet mixing and melt mixing, were compared. The electrical and thermal properties were analyzed. A high thermal conductivity value of about 0.741 W/(m K) could be obtained upon loading with 10 wt% Wh-CNTs and the PEEK/Wh-CNTs composites had low volume resistivity value of 10.96 Ω cm at 10 wt% loading via melt mixing. Thermal conductivity values of 1.066 W/(m K) (out-of-plane) and 1.50 W/(m K) (in-plane) were achieved with 10 wt% loading by wet mixing. Experimental results of out-of-plane thermal conductivity were more consistent with the Nan model. PEEK/Wh-CNTs composites prepared by wet mixing exhibited higher thermal conductivity than the composites mixed using the two other methods. As the content of Wh-CNTs in wet mixed PEEK/Wh-CNTs nanocomposites increased, electromagnetic interference (EMI) shielding effectiveness (SE) was improved. The PEEK/Wh-CNTs composites were 0.6 mm thick and showed an EMI SE of 21.5 dB. |
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Keywords: | extrusion manufacturing resins |
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