High electromagnetic interference shielding effectiveness achieved by multiple internal reflection and absorption in polybenzoxazine/graphene foams |
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Authors: | Shuai Zhang Hongyi Sun Tiange Lan Xiaobo Liu Qichao Ran |
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Affiliation: | 1. School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu, Sichuan, China;2. College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu, China |
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Abstract: | Electromagnetic interference (EMI) is an increasingly severe issue in modern life and high-performance EMI shielding materials are in desperate need. To achieve high EMI shielding effectiveness (EMI SE), a series of polybenzoxazine/graphene composites foams are developed using a simple sol–gel method. When the graphene loading increases from 1 to 20 wt%, the density of the composites foams drops from 0.4143 g/cm3 to 0.1654 g/cm3. Meanwhile, an electrically conductive path is formed at around 7 wt% of graphene. Below the percolation threshold, the dielectric constant increases with graphene content and composite foam with 5 wt% graphene shows dielectric constant of 10.8 (1 MHz). At the highest graphene content of 20 wt%, the electric conductivity reaches 0.02 S/cm, 10 orders of magnitude higher than pure polybenzoxazine foam. Benefiting from the high electrical conductivity and lightweight porous structure, the composite foam PF/20G delivers an EMI SE of 85 dB and a specific SE of 513.9 dB·cm3/g. Importantly, the EMI shielding is dominated by absorption attenuation, with PF/20G shows absorption ratio higher than 98% in the range of 8.4–11.0 GHz, which is believed to be caused by multiple internal reflection and absorption inside the conductive foam. |
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Keywords: | composites foams fullerenes graphene morphology nanoparticles nanowires and nanocrystals nanotubes |
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