|
|||||
|
|
Citric acid modified waste cigarette filters for adsorptive removal of methylene blue dye from aqueous solution |
|
| Authors: | Aafia Tehrim Min Dai Xiange Wu Malik Muhammad Umair Imran Ali Muhammad Ahsan Amjed Rong Rong Sheikh Fahad Javaid Changsheng Peng |
| Affiliation: | 1. The Key Lab of Marine Environmental Science and Ecology, Ministry of Education, College of Environmental Science and Engineering, Ocean University of China, Qingdao, China
School of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing, China;2. School of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing, China;3. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, China;4. The Key Lab of Marine Environmental Science and Ecology, Ministry of Education, College of Environmental Science and Engineering, Ocean University of China, Qingdao, China College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, China;5. The Key Lab of Marine Environmental Science and Ecology, Ministry of Education, College of Environmental Science and Engineering, Ocean University of China, Qingdao, China |
| Abstract: | Waste cigarette filters (CFs) were recycled and modified with a nontoxic and low-cost citric acid (CA). The modified CFs were employed in the adsorptive removal of methylene blue (MB) dye from aqueous medium. The influence of pH, contact time, initial dye concentration, and adsorbent dose on adsorption of MB dye was evaluated. The adsorption studies were conducted by employing linear and nonlinear Langmuir and Freundlich isotherm models. The adsorption capacity of CF obtained through linear and nonlinear Langmuir model were 88.02 and 94 mg g−1, which improved up to 163.93 and 168.81 mg g−1, respectively, after the introduction of functional groups in CF-CA. The adsorption kinetics data were well fitted by pseudo-second order kinetics with coefficient of regression (R2) closed to unity. The removal efficiency of CF-CA was 97% at equilibrium time of 4 h. Desorption studies indicated that CF-CA could be regenerated by using HCl (0.1 M) and desorption efficiency was up to 82% upon second cycle of reusability experiment. This study proposed a green and economical use of recycled CFs in dyes wastewater treatment, simultaneously reducing the negative environmental impact due to their improper disposal. |
| Keywords: | adsorption biopolymers and renewable polymers fibers |