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Functional nano-fillers in waterborne polyurethane/acrylic composites and the thermal,mechanical, and dielectrical properties |
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| Authors: | Xing Zhou Yonghua Song Dong Wang Changqing Fang Li Xie Taiping Yao Xin Zhang Jiawei Zhang |
| Affiliation: | 1. Faculty of Printing, Packaging Engineering and Digital Media Technology, Xi'an University of Technology, Xi'an, China;2. Faculty of Printing, Packaging Engineering and Digital Media Technology, Xi'an University of Technology, Xi'an, China School of Materials Science and Engineering, Xi'an University of Technology, Xi'an, China;3. School of Materials Science and Engineering, Xi'an University of Technology, Xi'an, China;4. Department of Electrical Engineering, Northeast Electric Power University, Jilin City, Jilin, China |
| Abstract: | Modification is mostly used to adjust and increase the performance of polymers by employing organic or inorganic fillers in composites. It is significant to investigate the functions of different fillers in polymer matrix. In this work, we prepared a series of composites by using polyurethane/acrylic dispersions as polymer matrix and nanofillers (cellulose nanocrystals, carbon nanotubes and aluminum oxide nanoparticles) as modifiers to study their micro-structure and applied performance. It is found that the different nanofillers can be dispersed in PUA homogenously, which are inclusive physically. Different nanofillers have a noticeable influence on the Tg for the acrylate copolymers and the Tg of the interphase between the acrylate and polyurethane. The CNTs significantly increases the elongation to 127.29%, and gives the highest dielectric response. We imply that the CNTs may be the most significant fillers to increase the mechanical and electrical properties. |
| Keywords: | blends coatings polyurethane thermal properties |