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Improved tribological and thermo-mechanical properties of epoxy resin with micro-nano structured ZrO2/Ti3C2 particles
Authors:Jie Yi  Yaru Yang  Yalin Zhang  Miao Cao  Tianle Wang  Jipeng Guan  Yunchao Xiao  Yuanjie Zhang  Bolin Tang  Xiaojun Shen
Affiliation:1. Key Laboratory of Yarn Materials Forming and Composite Processing Technology of Zhejiang Province, Jiaxing University, Jiaxing, China;2. School of Pharmaceutical and Materials Engineering, Taizhou University, Taizhou, China
Abstract:Inherent brittleness and poor wear resistance of epoxy resin severely restricts its practical application in many applications. In this present, a micro-nano structured ZrO2/Ti3C2 particle was employed to improve the tribological and thermo-mechanical properties of epoxy resin. The micro-nano structured ZrO2/Ti3C2 particles are synthesized by hydrothermal growth of nano-ZrO2 onto the surface of accordion-like Ti3C2, and the ZrO2/Ti3C2/epoxy composites are fabricated by solution blending and curing reaction. The surface morphology of ZrO2/Ti3C2 particles and the fracture surface of ZrO2/Ti3C2/epoxy composites were investigated. Test results indicated that the wear rate, storage modulus and glass transition temperature of epoxy resin is effectively improved by incorporation of ZrO2/Ti3C2 particles, maybe ascribing to the strong interfacial interaction between micro-nano structured ZrO2/Ti3C2 and epoxy matrix. In addition, the wear mechanism of ZrO2/Ti3C2/epoxy composites were further revealed by analyzing their worn surfaces and wear debris. This work provides a promising strategy for improving the tribological and thermo-mechanical properties of epoxy.
Keywords:composites  friction  mechanical properties  resins  thermosets  wear and lubrication
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