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多波长线性回归——导数分光光度法同时测定油品中的铁和钒
引用本文:李萍,赵杉林,孙虹,温忠斌,王秀英. 多波长线性回归——导数分光光度法同时测定油品中的铁和钒[J]. 辽宁石油化工大学学报, 1993, 0(1)
作者姓名:李萍  赵杉林  孙虹  温忠斌  王秀英
作者单位:抚顺石油学院应用化学系,抚顺石油学院应用化学系,抚顺石油学院应用化学系,抚顺石油学院应用化学系,抚顺石油二厂研究所
摘    要:用5-Br-PADAP 作显色剂,采用多波长线性回归一阶导数分光光度法同时测定油品中铁和钒,灵敏度高,ε铁=5.08×10~5L.mol~(-1)cm~(-1),ε铁=2.65×10~5Lmol~(-1)cm~(-1).铁和钒的最低检出限分别是0.005μgmL~(-1)和0.003μgmL.合成样品分析,加标实验及对照实验结果表明,该法简单、灵敏、准确。

关 键 词:多波长线性回归  导数分光光度法    

Simultaneous Determination of Iorn and Vanadium by Multi-Wavelength Linear Regression-Derivative Speetrophotometry
Li Ping Zhao Shanlin Shun Hong Wen Zhongbin. Simultaneous Determination of Iorn and Vanadium by Multi-Wavelength Linear Regression-Derivative Speetrophotometry[J]. Journal of Liaoning University of Petroleum & Chemical Technology, 1993, 0(1)
Authors:Li Ping Zhao Shanlin Shun Hong Wen Zhongbin
Abstract:In this paper,a method of simultaneous determination of iorn and vanadium by multi-wavelength linear regression derivative spectrophotometry is proposed.The milar absorptivities of iorn and vanadium are 5.08×10~5 and 2.65×10~5 respectively.The detec- tion limit are 0.005μg.mL~(-1) and 0.0003μg.mL~(-1).The result of performed experiments by adding standard sample is satisfactory.
Keywords:Multi-Wavelength linear  Regression  Derivative  Spectrophotometry Iorn  Vanadium
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