| 双-8-羟基喹啉高分子配合物的合成与应用 |
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| 引用本文： | 谭正德. 双-8-羟基喹啉高分子配合物的合成与应用[J]. 化学与粘合, 2005, 27(6): 328-331 |
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| 作者姓名： | 谭正德 |
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| 作者单位： | 湖南工程学院,化学化工系,湖南,湘潭,411104 |
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| 基金项目： | 国家民口配套材料资助项目（MKPT-04-237） |
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| 摘 要： | 用8-羟基喹啉在有相转移催化剂存在的碱性条件下,与氯仿作用合成5-甲酰基-8-羟基喹啉,然后将5-甲酰基-8-羟基喹啉分别与对苯二胺、联苯二胺,4,4＇-二氨基二苯砜反应,得到三种双-8-羟基喹啉-席夫碱配体,然后与金属离子配位,得到了一类新型的双-8-羟基喹啉-席夫碱-金属高分子配合物,再结合双-8-羟基喹啉-席夫碱配体与其它离子的显色反应,进行对比分析.利用红外光谱、紫外光谱对配体和配合物的结构进行表征,利用荧光光谱研究了高分子配合物的光致发光性能.
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| 关 键 词： | 高分子配合物 8-羟基喹啉 金属离子 |
| 文章编号： | 1001-0017（2005）06-0328-04 |
| 收稿时间： | 2005-05-08 |
| 修稿时间： | 2005-05-08 |
Preparation and Photoluminscent Property of Polymeric Dis( 8 - hydroxyquinoline Schiff base) Metal Iron Complexes |
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| TAN Zheng-de. Preparation and Photoluminscent Property of Polymeric Dis( 8 - hydroxyquinoline Schiff base) Metal Iron Complexes[J]. Chemistry and Adhesion, 2005, 27(6): 328-331 |
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| Authors: | TAN Zheng-de |
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| Affiliation: | Hunan Institute of Engineering,Xiangtan 411104, China |
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| Abstract: | Three types of ligands of Dis(8-hydroxyquinoline Schiff base) were prepared by reaction of 5-formyl-8-hydroxyquinoline,which was formed by reaction of bis(8-hydroxyquinoline) and chloroform,and three diamines(4,4'-phenylenediamline,4,4'-biphenyl-diamine and 4,4'-diamina-diaphenyl sulfone) respectively.Then the ligands were coordinated with metal iron to prepare three new polymeric bis(8-hydroxyquinoline schiff base)metal iron complex.The chemical structure of ligands and complexs was characterized by infrared absorption spectroscopy and ultraviolet absorption spectroscopy. |
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| Keywords: | polymeric complex, 8 - hydroxyquinoline zinc photoluminescence |
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