Abstract: | The mass-produced thermoplastics, PVC, polystyrene and polyolefins, have increasingly gained ground in fields of application where, during and after use, they are subjected as thin layers, e.g. in the form of films, to normal environmental influences. Degradation reactions on thin layers caused by heat and light in the presence of oxygen are gaining importance as much as a “controlled autoxidation” might open up new fields of application. Initiation and acceleration of autoxidation by ?potential sensitizers”? in the presence of oxygen and beams of light are critically evaluated with a view towards desired degradability. |