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Effect of polymer coating on ammonium nitrate substrate
Authors:Thomas C. Castorina  Andrew F. Smetana
Abstract:Prilled, spheroidized, and granular ammonium nitrates (AN) were coated with poly(chloro-p-xylylene) (parylene C) by a vapor deposition polymerization technique. Particles of AN with a 0.2% coating remain free flowing after long exposure to ambient conditions. The effectiveness of the coating as a moisture barrier on the three forms of AN was found to be in the order spheroids > prills > granules. Water adsorption isotherms and hygroscopicity determinations indicate that a 0.7% coating hydrophobes the surface of AN by approximately one order of magnitude. The parylene C/AN interface exhibits chemical and physical stability at elevated temperatures.
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