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Reaction dynamics in the combustion synthesis system of Al-CrO3-Al2O3-NaF-N2-O2
作者姓名:Dazheng  Yang  Yue  Zhang  Degang  Li  Dianwei  Qi  Wei  Deng  Dayong  Xun
作者单位:[1]Angang Steel Company Limited, Anshan 114001, China [2]State Key Lab for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China
基金项目:国家高技术研究发展计划(863计划)
摘    要:A new material with heat-resistant and adiabatic characteristics and high strength was prepared using the combustion synthesis method by mixed powders of CrO3, Al, Al2O3, and NaF in atmospheric gas. The reaction dynamic process of the Al-CrO3-NaF-Al2O3-N2-O2 new material system by the combustion synthesis method was discussed based on the observation results by SEM, EDS, and XRD in combination with the combustion front quenching method (CFQM) and the relation curves between reaction free enthalpies and the corresponding temperatures. The combustion synthesis mechanism and the formation reasons of the phase in the combustion product were analyzed.

关 键 词:燃烧前淬火法  反应过程  反应动力学  燃烧合成  隔热材料  氧化铝  氧化铬
收稿时间:8 August 2006. 
修稿时间:2006-08-08

Reaction dynamics in the combustion synthesis system of Al-CrO3-Al2O3-NaF-N2-O2
Dazheng Yang Yue Zhang Degang Li Dianwei Qi Wei Deng Dayong Xun.Reaction dynamics in the combustion synthesis system of Al-CrO3-Al2O3-NaF-N2-O2[J].Journal of University of Science and Technology Beijing,2007,14(3):261-265.
Authors:Dazheng Yang  Yue Zhang  Degang Li  Dianwei Qi  Wei Deng  Dayong Xun
Affiliation:1. Angang Steel Company Limited, Anshan 114001, China;State Key Lab for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China
2. State Key Lab for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China
3. Angang Steel Company Limited, Anshan 114001, China
Abstract:A new material with heat-resistant and adiabatic characteristics and high strength was prepared using the combustion synthesis method by mixed powders of CrO3, Al, Al2O3, and NaF in atmospheric gas. The reaction dynamic process of the Al-CrO3-NaF-Al2O3-N2-O2 new material system by the combustion synthesis method was discussed based on the observation results by SEM,EDS, and XRD in combination with the combustion front quenching method (CFQM) and the relation curves between reaction free enthalpies and the corresponding temperatures. The combustion synthesis mechanism and the formation reasons of the phase in the combustion product were analyzed.
Keywords:combustion front quenching method (CFQM)  reaction process  combustion synthesis (CS)  adiabatic materials
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