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Microstructure and electrical properties of Y2O3-doped ZnO-based varistor ceramics prepared by high-energy ball milling
作者姓名:Hongyu  Liu  Xueming  Ma  Dongmei  Jiang  Wangzhou  Shi
作者单位:[1]College of Science, Wuhan University of Science and Technology, Wuhan 430081, China [2]Department of Physics, East China Normal University, Shanghai 200062, China
摘    要:Y2O3-doped ZnO-based varistor ceramics were prepared using high-energy ball milling (HEBM) and low-temperature sin- tering technique, with voltage-gradient of 1934-2197 V/mm, non-linear coefficients of 20.8-21.8, leakage currents of 0.59-1.04 μA, and densities of 5.46-5.57 g/cm3. With increasing Y2O3 content, the voltage-gradient increases because of the decrease of ZnO grain size; the non-linear coefficient and the leakage current improve but the density decreases because of more porosity; the donor con- centration and density of interface states decrease, whereas the barrier height and width increase because of the acceptor effect of Y2O3 in varistor ceramics.

关 键 词:球磨研磨  显微结构  电学特性  氧化锌  氧化钇  变阻器  陶瓷  低温烧结
收稿时间:14 July 2006. 
修稿时间:2006-07-14

Microstructure and electrical properties of Y2O3-doped ZnO-based varistor ceramics prepared by high-energy ball milling
Hongyu Liu Xueming Ma Dongmei Jiang Wangzhou Shi.Microstructure and electrical properties of Y2O3-doped ZnO-based varistor ceramics prepared by high-energy ball milling[J].Journal of University of Science and Technology Beijing,2007,14(3):266-270.
Authors:Hongyu Liu  Xueming Ma  Dongmei Jiang  Wangzhou Shi
Affiliation:1. College of Science, Wuhan University of Science and Technology, Wuhan 430081, China
2. Department of Physics, East China Normal University, Shanghai 200062, China
Abstract:Y2O3-doped ZnO-based varistor ceramics were prepared using high-energy ball milling (HEBM) and low-temperature sintering technique, with voltage-gradient of 1934-2197 V/mm, non-linear coefficients of 20.8-21.8, leakage currents of 0.59-1.04 μA,and densities of 5.46-5.57 g/cm3. With increasing Y2O3 content, the voltage-gradient increases because of the decrease of ZnO grain size; the non-linear coefficient and the leakage current improve but the density decreases because of more porosity; the donor concentration and density of interface states decrease, whereas the barrier height and width increase because of the acceptor effect of Y2O3 in varistor ceramics.
Keywords:inorganic materials  electrical properties  high-energy ball milling  varistor  microstructure  low-temperature sintering  zinc oxide  yttrium oxide
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