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负载金属改性活性炭纤维的脱硫性能
引用本文:王建英,赵风云,胡永琪,赵瑞红,刘润静.负载金属改性活性炭纤维的脱硫性能[J].中国化学工程学报,2006,14(4):478-485.
作者姓名:王建英  赵风云  胡永琪  赵瑞红  刘润静
作者单位:College or Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang050018, China
摘    要:Metal-loaded activated carbon fibers (ACFs) were prepared by impregnation and characterized by N2 adsorption at 77K, XRD, XPS and SEM. Their properties on SO2 removal were examined in a tubular fixed bed reactor with a model flue gas. Cobalt-loaded ACF showed the best activity among the prepared metal-loaded ACFs and a constant removal ratio of SO2 above 87% during continuous exposure to the flow of SO2/O2/H2O/N2 at 45℃ for more than 216h. The characteristic of the prepared loaded-ACFs showed that the exceptional activity of Co-ACF was attributed to the high amount of active sites due to modification by loading cobalt.

关 键 词:负载金属改性  活性炭纤维  脱硫性能  吸附性质
收稿时间:2005-05-09
修稿时间:2005-05-092006-02-13

Modification of Activated Carbon Fiber by Loading Metals and Their Performance on SO2 Removal
Jianying WANG, Fengyun ZHAO, Yongqi HU, Ruihong ZHAO,Runjing LIU.Modification of Activated Carbon Fiber by Loading Metals and Their Performance on SO2 Removal[J].Chinese Journal of Chemical Engineering,2006,14(4):478-485.
Authors:Jianying WANG  Fengyun ZHAO  Yongqi HU  Ruihong ZHAO  Runjing LIU
Affiliation:College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China;College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China;College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China;College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China;College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China
Abstract:Metal-loaded activated carbon fibers (ACFs) were prepared by impregnation and characterized by N2adsorption at 77K, XRD, XPS and SEM. Their properties on SO2 removal were examined in a tubular fixed bed reactor with a model flue gas. Cobalt-loaded ACF showed the best activity among the prepared metal-loaded ACFs and a constant removal ratio of SO2 above 87% during continuous exposure to the flow of SO2/O2/H2O/N2 at 45℃ for more than 216h. The characteristic of the prepared loaded-ACFs showed that the exceptional activity of Co-ACF was attributed to the high amount of active sites due to modification by loading cobalt.
Keywords:activated carbon fiber  impregnation  adsorption properties
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