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荧光手性聚芳硫醚酰亚胺季胺盐的制备及表征
引用本文:刘春丽,张冠星,陈成坤,龙盛如,杨杰.荧光手性聚芳硫醚酰亚胺季胺盐的制备及表征[J].功能材料,2007,38(8):1313-1315,1319.
作者姓名:刘春丽  张冠星  陈成坤  龙盛如  杨杰
作者单位:1. 四川大学,化学学院,四川,成都,610064
2. 四川大学,高分子科学与工程学院,四川,成都,610064
3. 四川大学,材料科学技术研究所,四川,成都,610064
基金项目:国家高技术研究发展计划(863计划)
摘    要:在制备PASI的基础上制备ASIHC,通过红外分析,核磁共振,紫外分析表征PASIHC的结构,旋光测试表明PASIHC具有手性结构,热分析表明PASIHC的热性能较聚芳硫醚酰亚胺略有升高.荧光分析表明PASIHC具有荧光性能.PASIHC作为光学器件和热敏元件具有良好的应用前景.为制备含有N原子的聚芳硫醚类树脂提供基础数据,为制备具有荧光性能和手性结构的聚芳硫醚类树脂提供新思路.

关 键 词:聚芳硫醚酰亚胺  聚芳硫醚酰亚胺季胺盐  荧光
文章编号:1001-9731(2007)08-1313-03
修稿时间:2006-12-272007-05-31

Prepared and elucidated chirality structure of quaternary ammonium salt of polyarylene imide sulfide hydrochloride and its fluorescent light and thermal properties
LIU Chun-li,ZHANG Guan-xing,CHEN Cheng-kun,LONG Sheng-ru,YANG Jie.Prepared and elucidated chirality structure of quaternary ammonium salt of polyarylene imide sulfide hydrochloride and its fluorescent light and thermal properties[J].Journal of Functional Materials,2007,38(8):1313-1315,1319.
Authors:LIU Chun-li  ZHANG Guan-xing  CHEN Cheng-kun  LONG Sheng-ru  YANG Jie
Abstract:The quaternary ammonium salt of polyarylene imide sulfide hydrochloride(PASIHC) was prepared firstly and elucidated by FT-IR,H1-NMR,UV,polarimetric method,fluoremetry.The results showed that the polyarylene imide sulfide hydrochloride was formed and it was stereo-isomerism and fluorescent materials.The results of DSC and TG showed that the PASIHC possessed good thermal stability and heat-variable.The basis datum and good idea were given for preparing polyarylene sulfide containing nitrogen or chirality and the PASIHC will be applied abroad.
Keywords:polyarylene imide sulfide  polyarylene imide sulfide hydrochloride  fluorescent light
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