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| 新型高分子材料——聚亚胺酮的合成与性能研究 | |
| 引用本文： | 常冠军,贾献彬,罗炫,刘志坡,高爱娟,刘华,唐世振,张林,林润雄.新型高分子材料——聚亚胺酮的合成与性能研究[J].化学推进剂与高分子材料,2008,6(3). |
| 作者姓名： | 常冠军 贾献彬 罗炫 刘志坡 高爱娟 刘华 唐世振 张林 林润雄 |
| 作者单位： | 1. 中国工程物理研究院,四川绵阳,621900;青岛科技大学橡塑材料与工程教育部重点实验室,山东青岛,266042 2. 中国工程物理研究院,四川绵阳,621900 3. 青岛科技大学橡塑材料与工程教育部重点实验室,山东青岛,266042 4. 中国海洋大学工程学院,山东青岛,266100 |
| 摘 要： | 通过傅-克酰基化反应合成了1,4-双-(4′-溴苯酰基)苯。以1,4-双-(4′-溴苯酰基)苯和芳香二胺为单体,通过钯催化的胺基化反应缩聚合成了新型高性能聚合物——聚亚胺酮(PIKs)。其结构由红外和核磁氢谱表征,表征结果与目标结构吻合良好。通过差示扫描量热仪(DSC)和热重分析(TG)等对PIKs的主要性能进行了测定,研究表明:该系聚合物有较高的玻璃化转变温度(Tg>230℃)、良好的热稳定性(高的热分解温度TD>500℃)及优秀的的溶解性能,其中PIK-3在室温下(20℃)可溶解在普通有机溶剂三氯甲烷(CHCl3)中。 |
| 关 键 词： | 1 4-双-(4′-溴苯酰基)苯 芳香二胺 钯催化 配体 聚亚胺酮 |
Study on Synthesis and Properties of A Novel Polymer Material Poly(Imino Ketone) |
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| CHANG Guan-jun,JIA Xian-bin,LUO Xuan,LIU Zhi-po,GAO Ai-juan,LIU Hua,TANG Shi-zhen,ZHANG Lin,LIN Run-xiong.Study on Synthesis and Properties of A Novel Polymer Material Poly(Imino Ketone)[J].Chemical Propellants & Polymeric Materials,2008,6(3). | |
| Authors: | CHANG Guan-jun JIA Xian-bin LUO Xuan LIU Zhi-po GAO Ai-juan LIU Hua TANG Shi-zhen ZHANG Lin LIN Run-xiong |
| Abstract: | 1,4-bis-(4-bromobenzoyl)benzene was synthesized by Friedel-Crafts benzoylation reaction. Novel poly(imino ketone) s (PIKs) as high performance polymers were obtained by the condensation polymerization of 1,4-bis-(4-bromobenzoyl)benzene and aromatic diamines as the monomers via palladium-catalyzed amination reaction. The strcture of PIKs are characterized by means of FT- IR and 1H-NMR spectroscopy, and the results agree with the proposed purpose structure. DSC and TG measurements show that PIKs possess high glass transition temperature(Tg>230℃), good thermal stability with high decomposition temperatures(TD>500℃) and excellent solubility. PIK-3 can be dissolved in common organic solvent CHCl3 at room temperature(20℃). |
| Keywords: | 1 4-bis-(4-bromobenzoyl)benzene aromatic diamine palladium-catalyzed ligand poly(imino ketone) |
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