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有机-无机纳米复合光折变材料的合成研究
引用本文:吴仪温,黄俊,赵俊,童杏林.有机-无机纳米复合光折变材料的合成研究[J].武汉理工大学学报,2005,27(5):12-14.
作者姓名:吴仪温  黄俊  赵俊  童杏林
作者单位:武汉理工大学光纤传感技术研究与开发中心,武汉,430070
摘    要:有机-无机纳米复合光折变材料具有优异的光折变性能和重要的应用前景。以PVK基掺杂型光折变体系为基础,制备了一种新型的光折变材料,并对其进行了表征。合成了低玻璃化温度的非线性分子DMNPAT,通过增加烷氧基的长度降低光折变体系玻璃化温度;采用化学复合方法在电荷传输体PVK上复合GdS半导体纳米粒子作为光敏剂,提高体系的光导性,可望具有较好的光折变性能。

关 键 词:光折变  非线性分子  有机-无机纳米复合  光导性
文章编号:1671-4431(2005)05-0012-03
修稿时间:2004年12月12

Preparations and Properties of Organic-inorganic Nanoparticles Hybrid Photorefractive Material
WU Yi-wen,HUANG Jun,ZHAO Jun,TONG Xing-lin.Preparations and Properties of Organic-inorganic Nanoparticles Hybrid Photorefractive Material[J].Journal of Wuhan University of Technology,2005,27(5):12-14.
Authors:WU Yi-wen  HUANG Jun  ZHAO Jun  TONG Xing-lin
Abstract:Organic-inorganic nanoparticles hybrid photorefractive material has significant future prospect due to its promising characteristics. In this paper, it reporte d on the preparations and characterizations of a novel organic-inorganic nanopa rticles hybrid photorefractive material in which PVK served as a polymeric charg e-transporting matrix.DMNPAT with low T g was prepared to serve as nonline ar optical chromophores. In this material, CdS nanoparticles that were doped in the PVK by chemically hybridization served as a charge-generating agent to increase the photoconduct ivity and this kind of material will probably have good photorefractivity.
Keywords:photorefractivity  nonlinear optical chromophor e  organic-inorganic hybrid  photoconductivity
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