Abstract: | By thermally treating a commercial cellulose in ethylene glycol, celluloses of controlled low degree of polymerization, DPr = 1000 to 70, can be derived. Two general behaviors are observed in the range studied. At first, the depolymerization reaction is predominant down to a DP equal to 130. Beyond this level, the depolymerization process leads to extensive solubilization of the cellulose. The treated celluloses have been analyzed by X-ray diffraction, FTIR, TGA, elemental analysis and enzymatic hydrolysis. No chemical change of the cellulose could explain the two different behaviors. A physical modification in the form of depolymerization and destructuration is suspected. |