| 三光气法合成双酚S/双酚A共聚碳酸酯 |
| |
| 引用本文： | 陈晓婷,李恺军,唐旭东.三光气法合成双酚S/双酚A共聚碳酸酯[J].合成技术及应用,2007,22(2):11-13. |
| |
| 作者姓名： | 陈晓婷 李恺军 唐旭东 |
| |
| 作者单位： | 天津科技大学材料科学与化学工程学院,天津,300457 |
| |
| 摘 要： | 以双酚A、双酚S和三光气为单体,通过界面缩聚合成了共聚碳酸酯。研究了聚合反应温度、三光气、氢氧化钠及催化剂用量以及油水比等因素对聚合反应的影响,得到特性粘数为1．28 dL/g的聚碳酸酯共聚物。采用FT-IR确定了产物的结构;共聚碳酸酯的玻璃化转变温度为157．9℃,极限氧指数为0．32。
|
| 关 键 词： | 聚碳酸酯 三光气 双酚S 阻燃 共聚 |
| 文章编号： | 1006-334X（2007）02-0011-03 |
| 收稿时间： | 2007-04-23 |
| 修稿时间： | 2007-04-23 |
Synthesis of copolycarbonate by triphosgene and bisphenol S/bisphenol A |
| |
| Chen Xiaoting,Li Kaijun,Tang Xudong.Synthesis of copolycarbonate by triphosgene and bisphenol S/bisphenol A[J].Synthetic Technology and Application,2007,22(2):11-13. |
| |
| Authors: | Chen Xiaoting Li Kaijun Tang Xudong |
| |
| Abstract: | Copolycarbonate was prepared by interracial polycondensation of bisphenol A,bisphenol S and triphos- gene in the dichloromethane/aqueous NaOH system.The influences of factors on the polymerization were investigated, such as the reaction temperature,the amount of BTC,NaOH,TMBA,and the volume of organic phase.The copolycar- bonate with intrinsic viscosity of 1.28 was obtained.The structure of the polymer was characterized by FT-IR.The result of DSC shows that the Tg of the PC is 157.9℃.The LOI of the copolycarbonate is 0.32. |
| |
| Keywords: | polycarbonates triphosgene bisphenol S flame retardancy copolmerization |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
