Hydrogen absorption and desorption properties of Mg/MgH2 with nanometric dispersion of small amounts of Nb(V) ethoxide |
| |
Authors: | Xavier A Ojeda Facundo J Castro Santiago A Pighin Horacio E Troiani M Sergio Moreno Guillermina Urretavizcaya |
| |
Affiliation: | 1. Instituto Sábato, Universidad Nacional de San Martín, 25 de Mayo y Francia, San Martín, Argentina;2. Instituto Balseiro, Universidad Nacional de Cuyo, Av. Bustillo 9500, S.C. de Bariloche, Argentina;3. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), CNEA, Centro Atómico Bariloche, Av. Bustillo 9500, S.C. de Bariloche, Argentina;4. Centro Regional Universitario Bariloche, Universidad Nacional Del Comahue, Quintral 1250, S.C. de Bariloche, Argentina;5. Instituto de Nanociencia y Nanotecnología, INN CNEA-CONICET, Centro Atómico Bariloche, Av. Bustillo 9500, S.C. de Bariloche, Argentina |
| |
Abstract: | A study to determine the optimal content of Nb(V) ethoxide required to efficiently catalyze the H2 sorption kinetics in the Mg/MgH2 system is reported. The materials were synthesized by hand mixing different amounts of additive (from 0.10 to 1 mol%) to pre-milled MgH2. Considering kinetics and capacity the best performance corresponds to a 0.25 mol% of Nb ethoxide concentration. With this material, a remarkable kinetic behavior with excellent reversibility is obtained: 5.3 wt% and 5.1 wt% of hydrogen are absorbed and desorbed respectively at 300 °C in 3 min. At 250 °C the material absorbs 5.2 wt% of hydrogen and releases 3.7 wt% in 10 min. Thermal desorption starts at 247 °C and peaks at 268 °C. The H2 sorption properties of all the materials remain unchanged after 10 cycles of absorption and desorption at 300 °C, and the best material reversibly takes in and releases 5.3 wt% of H2 during a 10 min combined cycle. The kinetic improvement of the hydrogen desorption and absorption properties is attributed to an enhancement of the kinetic processes that occur on the surface of the material, due to the excellent spreading of the liquid additive at nanometric level, as revealed by SEM/EDS and TEM/EELS. |
| |
Keywords: | Hydrogen storage Niobium alkoxide TEM/EELS Kinetics |
本文献已被 ScienceDirect 等数据库收录! |
|