Fuel cells for carbon capture and power generation: Simulation studies |
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Authors: | Remston Martis Amani Al-Othman Malek Alkasrawi Muhammad Tawalbeh |
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Affiliation: | 1. Department of Chemical Engineering, American University of Sharjah, PO Box 26666, Sharjah, United Arab Emirates;2. Department of PS & Chemical Engineering, University of Wisconsin, Stevens Point, USA;3. Sustainable and Renewable Energy Engineering Department, University of Sharjah, Sharjah, United Arab Emirates |
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Abstract: | The decarbonization of hydrocarbons is explored in this work as a method to produce hydrogen and mitigate carbon dioxide (CO2) emissions. An integrated process for power generation and carbon capture based on a hydrocarbon fueled-decarbonization unit was proposed and simulated. Ethane and propane were used as fuels and subjected to the thermal decomposition (decarbonization) process. The system is also composed of a carbon fuel cell (CFC) and hydrogen fuel cell (HFC) for the production of power and a pure CO2 stream that is ready for sequestration. The HFC is a high-temperature proton exchange membrane fuel cell operating at 200 °C. Simulations were performed using ASPEN HYSYS V.10 for the entire process including the CFC and HFC being operated at various operating temperatures (200–800 °C). The power output from the CFC and the HFC as well as the overall process efficiency were calculated. The model incorporates an energy recovery system by adopting a counter-current shell and tube heat exchangers and a turbine. The water produced from the fuel cell system can be utilized in the plant to recover the heat from the furnace. The results showed a 100% carbon capture with a nominal plant capacity of 108 MWe produced when propane fuel was fed to the decarbonizer. The CFC theoretical efficiency is 100% and the practical efficiency was taken as 70% when all internal polarizations were considered. The results showed that, in the case of propane, the CFC power output was 89 MWe when the CFC operated at 650 °C, and the HFC power output was around 45 MWe at 200 °C with an overall actual plant efficiency of 35% and 100% carbon capture. Sensitivity analysis recommends a hydrocarbon fuel cost of 0.011 $/kW as the most feasible option. The results reported here on the decarbonization of hydrocarbon fuels are promising toward the direct production of hydrogen with full carbon dioxide sequestration at a potentially lower cost especially in rural areas. The overall actual efficiencies are very competitive to those of conventional power plants operated without carbon capture. |
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Keywords: | Direct carbon fuel cells Hydrocarbon fuels Decarbonization Carbon capture ASPEN HYSYS Sensitivity analysis |
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