Enhanced photocurrent by MOFs layer on Ti-doped α-Fe2O3 for PEC water oxidation

Low photocurrent density of hematite (α-Fe₂O₃) originating from the inherent defects usually hinders its application in photoelectrochemical (PEC) water oxidation. In this paper, the synergetic effect of increase of oxygen vacancies and in-situ constructing heterojunction by coating MOFs on the α-Fe₂O₃ nanoarrays gives rise to the boosted photocurrent of α-Fe₂O₃ from 0.25 mA/cm² to 2.1 mA/cm² at 1.23 V (vs. RHE). The results showed that the appropriate energy band structure engineered by the presence of MOFs layer not only facilitated the PEC water oxidation, but also enhanced the light absorption performance. With inducing oxygen vacancies in further, the intrinsic conductivity of photoanode can be well ameliorated. The value of carrier density is improved one order higher to promote charge transfer between the interfaces and raise the carrier separation efficiency as a result.