Innovative hydrogen release from sodium borohydride hydrolysis using biocatalyst-like Fe2O3 nanoparticles impregnated on Bacillus simplex bacteria |
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Authors: | Sibel Duman Bülent Kaya Fatma Caf Barış Enez Sema Aguloğlu Fincan |
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Affiliation: | 1. Department of Chemistry, Faculty of Arts and Sciences, Bingol University, 12000, Bingol, Turkey;2. Department of Molecular Biology and Genetics, Faculty of Arts and Sciences, Bingol University, 12000, Bingol, Turkey;3. Department of Veterinary, Vocational School of Technical Sciences, Bingol University, 12000, Bingol, Turkey;4. Department of Molecular Biology and Genetics, Faculty of Arts and Sciences, Dicle University, Diyarbakir, Turkey |
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Abstract: | For the first time in this innovative study, microorganisms such as Bacillus simplex bacteria, mostly used in biological activity studies, are used as a bio-supporter agent of iron to release hydrogen from sodium borohydride hydrolysis at 25.0 ± 0.1 °C. The goal is to investigate thoroughly sodium borohydride hydrolysis catalyzed by Fe2O3 nanoparticles impregnated on microorganism such as Bacillus simplex (BS) bacteria (Fe2O3@BS NPs) known with strong antibacterial properties, which makes innovative them a candidate for hydrolysis reaction. This study was focused on the preparation, identification, and catalytic use of biocatalyst-like Fe2O3@BS NPs for hydrogen release from the sodium borohydride hydrolysis at 25.0 ± 0.1 °C. The characterization results made after and before hydrolysis reaction using by SEM/SEM-EDX, FT-IR, XRD, UV–vis, XPS, DLS, ELS Zeta potential, ESR, and TEM techniques reveal the formation of highly active, stable, durable, and long-lived biocatalysts-like Fe2O3@BS NPs. |
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Keywords: | Bacillus simplex Bacteria Bio-supporter Sodium borohydride hydrolysis Iron catalyst |
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