| 硝氧乙基硝胺系列化合物的合成与表征 |
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| 引用本文： | 高福磊,姬月萍,李普瑞,刘卫孝,汪营磊,兰英,刘亚静. 硝氧乙基硝胺系列化合物的合成与表征[J]. 含能材料, 2011, 19(5): 497-500. DOI: 10.3969/j.issn.1006-9941.2011.05.003 |
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| 作者姓名： | 高福磊 姬月萍 李普瑞 刘卫孝 汪营磊 兰英 刘亚静 |
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| 作者单位： | 西安近代化学研究所,陕西西安,710065 |
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| 基金项目： | 武器装备部预研基金项目（51328050505） |
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| 摘 要： | 分别以甲基乙醇胺、乙基乙醇胺、丁基乙醇胺为原料,通过乙酸酐/硝酸法合成得到甲基硝氧乙基硝胺(Me-NENA)、乙基硝氧乙基硝胺(Et-NENA)、丁基硝氧乙基硝胺(Bu-NENA)三种化合物,并采用核磁共振、红外光谱、元素分析等鉴定了其结构；通过正交实验,以反应温度、时间、乙酸酐和浓硝酸用量等为因素,研究其对Et-NE...
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| 关 键 词： | 有机化学 含能增塑剂 合成 性能 |
| 收稿时间： | 2010-11-02 |
| 修稿时间： | 2011-05-17 |
Synthesis and Characterization of N-(2-Nitroxyethyl) alkylnitramines |
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| GAO Fu-lei,JI Yue-ping,LI Pu-rui,LIU Wei-xiao,WANG Ying-lei,LAN Ying and LIU Ya-jing. Synthesis and Characterization of N-(2-Nitroxyethyl) alkylnitramines[J]. Chinese Journal of Energetic Materials, 2011, 19(5): 497-500. DOI: 10.3969/j.issn.1006-9941.2011.05.003 |
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| Authors: | GAO Fu-lei JI Yue-ping LI Pu-rui LIU Wei-xiao WANG Ying-lei LAN Ying LIU Ya-jing |
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| Affiliation: | GAO Fu-lei,JI Yue-ping,LI Pu-rui,LIU Wei-xiao,WANG Ying-lei,LAN Ying,LIU Ya-jing(Xi'an Modern Chemistry Research Institute,Xi'an 710065,China) |
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| Abstract: | N-Methyl-N-(2-nitroxyethyl)nitramine(Me-NENA),N-ethyl-N-(2-nitroxyethyl)nitramine(Et-NENA) and N-butyl-N-(2-nitroxyethyl)nitramine(Bu-NENA) were prepared by the reactions of methyl ethanolamine,ethyl ethanolamine,butyl ethanolamine and nitric acid,acetic anhydride respectively.The structure of the target products were identified by 1H NMR,IR and elemental analysis.The parameters affecting the yield and purity of Et-NENA,such as temperature,reaction time,nitric acid and acetic anhydride were discussed.The op... |
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| Keywords: | organic chemistry energetic plasticizer synthesis property |
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