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Having it both ways: delicate hierarchical structure and robust mechanical stability on micro/nanomaterials with mesoporous silica coating
Authors:Zhi-Min Cui  Jing Hao  Chang-Yan Cao  Weiguo Song
Affiliation:1.Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, Beijing Key Laboratory of Bio-inspired Energy Materials and Devices, School of Chemistry and Environment,Beihang University,Beijing,People’s Republic of China;2.National Laboratory for Molecular Science, Institute of Chemistry,Chinese Academy of Sciences,Beijing,People’s Republic of China
Abstract:Mesoporous silica (meso-SiO2) was coated on the micro/nanomaterials with hierarchical structure such as flowerlike Fe2O3, flowerlike MgO, SnO2 nanospheres, Co3O4 nanosheets and nanowires from a simple solution method. The structure of the nanomaterials and the silica coating before and after stirring in solution were characterizated by SEM and TEM. The results show that meso-SiO2 coating was an ideal method to enhance the structural stability of fragile nanomaterials. The catalysis stability of flowerlike MgO was also enhanced by the meso-SiO2 coating.
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