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Low-cost preparation of a conductive and catalytic graphene film from chemical reduction with AlI3
Authors:Xiaochong Zhao  Hong Lin  Junfeng Li  Li Xin  Chenyang Liu  Jianbao Li
Affiliation:1. State Key Laboratory of New Ceramics & Fine Processing, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, China;2. MEMS Center, Pen-Tung Sah Institute of Micro-Nano Science and Technology, Xiamen University, Xiamen 361005, China;3. Key Laboratory for Hainan Advantage Resources and Applied Technology in Chemical Engineering Material of Ministry of Education, Hainan Provincial Key Laboratory of Research on Utilization of Si-Zr-Ti, Materials and Chemical Engineering Institute, Hainan University, Haikou 570228, China
Abstract:AlI3 synthesized by I2 and Al in ethanol was used as reductive agent to directly obtain flexible reductive graphene oxide (RGO) films with high conductivity of 5320 S/m from graphene oxide (GO) films at a low temperature of 80 °C. This reductive method has provided a low-cost and effective route for large-scale production of graphene with high catalytic activity. Structural evolution during the reduction of GO was studied by Fourier-transform infrared spectroscopy and X-ray photoelectron spectroscopy. The RGO films served as counter electrode exhibited high electrochemical activity.
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