The formation of a hydrothermal carbon coating on graphite microfiber felts for using as structured acid catalyst |
| |
Authors: | Laura Roldán Iván Santos Sabino Armenise José María Fraile Enrique García-Bordejé |
| |
Affiliation: | 1. Instituto de Carboquimica (ICB-CSIC), Miguel Luesma Castán 4, 50018 Zaragoza, Spain;2. Instituto de Síntesis Química y Catálisis Homogénea, Facultad de Ciencias, Universidad de Zaragoza – CSIC, Pedro Cerbuna 12, 50009 Zaragoza, Spain |
| |
Abstract: | A hydrothermal carbon layer has been coated on graphite felt using a carbohydrate solution (glucose, sucrose or starch) as precursor. The coating is uniform in thickness and coverage, and exhibits excellent adhesion to the substrate. It is highly hydrophilic, very accessible to reactants and the thickness can be tuned by the synthesis conditions. The coating was functionalized with sulfonic acid groups and its morphology and surface chemistry characterized by SEM, TPO-MS, IR-spectroscopy and XPS. The sulfonated material has been tested in the esterification of palmitic acid with methanol exhibiting significant activity and stability. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|