Hollow micro-mesoporous carbon polyhedra produced by selective removal of skeletal scaffolds

An approach has been demonstrated for fabricating hollow micro-mesoporous carbon polyhedra by selective removal of the skeletal scaffolds of polyurethane (PU) foam in monolithic mesostructured resin/PU composites. Hollow micro-mesoporous carbon polyhedra with an irregular shape molded from the cellular cavities of PU foam were synthesized by using phenolic resol as a precursor, triblock copolymer Pluronic F127 as a template, PU foam as a skeletal scaffold and triethyl phosphate as a reaction agent. By a reaction with triethyl phosphate, the PU foam in resin/PU composites can be degraded, simultaneously leading to the disassembly of the monolithic structure into separated polyhedral particles. The method can also be used for synthesizing hollow micro-mesoporous carbon–silica polyhedra, using tetraethyl orthosilicate as a silica source. Moreover, after etching the silica away, hollow micro-mesoporous carbon polyhedra with an ordered hexagonal mesostructure (space group p6mm), large particle sizes of 65–500 μm, a large surface area of 1384 m² g^?1, a uniform pore size of 3.2 nm and a high pore volume of 1.15 cm³ g^?1 as well as a high mesoporosity of 81% can be obtained, which exhibits excellent adsorption performance toward methylene blue compared with the active carbon having a similar surface area.