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Polyamine-functionalized carbon quantum dots for chemical sensing
Authors:Yongqiang Dong  Ruixue Wang  Hao Li  Jingwei Shao  Yuwu Chi  Xiaomei Lin  Guonan Chen
Affiliation:MOE Key Laboratory of Analysis and Detection Technology for Food Safety, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, and Department of Chemistry, Fuzhou Univiersity, Fujian 350108, China
Abstract:Polyamine-functionalized carbon quantum dots (CQDs) with high fluorescence quantum yield (42.5%) have been synthesized by the low temperature (<200 °C) carbonization of citric acid with branched polyethylenimine (BPEI) in one simple step. The obtained BPEI–CQDs are spherical graphite nanocrystals (average 6.2 nm in size) capped with abundant BPEI at their surfaces. It is the first report that CQDs are both amino-functionalized and highly fluorescent, which suggests their promising applications in chemical sensing.
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