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Suppression of wear in graphene polymer composites
Authors:Sashi S Kandanur  Mohammad A Rafiee  Fazel Yavari  Michael Schrameyer  Zhong-Zhen Yu  Thierry A Blanchet  Nikhil Koratkar
Affiliation:1. Department of Mechanical, Aerospace and Nuclear Engineering, Rensselaer Polytechnic Institute, 110 8th Street, Troy, NY 12180-3590, USA;2. Department of Materials Science and Engineering, Rensselaer Polytechnic Institute, 110 8th Street, Troy, NY 12180-3590, USA;3. State Key Laboratory of Organic-Inorganic Composites, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Abstract:Polytetrafluoroethylene (PTFE) is one of the most widely used solid lubricants but suffers from a high wear rate which limits its applications. Here we report four orders of magnitude reduction in the steady state wear rate of PTFE due to graphene additives. The wear rate of unfilled PTFE was measured to be ~0.4 × 10?3 mm3/N m which is reduced to ~10?7 mm3/N m by the incorporation of 10 wt% of graphene platelets. We also performed a head-to-head comparison of wear rate with graphene and micro-graphite fillers at the same weight fractions. In general, we find that graphene fillers gave 10–30 times lower wear rates than micro-graphite at the same loading fraction. Scanning electron microscopy analysis indicated noticeably smaller wear debris size in the case of graphene/PTFE composites indicating that graphene additives are highly effective in regulating debris formation in PTFE leading to reduced wear.
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