| 清洁氧化法合成己二酸 |
| |
| 引用本文： | 张付利,杨诗敬,张萌.清洁氧化法合成己二酸[J].河南化工,2006,23(11):15-16. |
| |
| 作者姓名： | 张付利 杨诗敬 张萌 |
| |
| 作者单位： | 河南大学医学院河南开封475001;开封开化(集团)有限公司河南开封475002 |
| |
| 基金项目： | 河南省科技厅科技攻关项目 |
| |
| 摘 要： | 以30%的双氧水为氧源, 钨酸钠为催化剂,KF-101为助催化剂,催化氧化环己烯清洁合成己二酸,考察了助催化剂、催化剂用量、反应物物质的量比、反应时间等对反应的影响,通过正交实验确定优化条件,在优化条件下,己二酸收率达93%.
|
| 关 键 词： | 己二酸 环己烯 过氧化氢 清洁氧化 |
| 文章编号： | 1003-3467（2006）11-0015-02 |
| 收稿时间： | 2006-10-09 |
| 修稿时间： | 2006-10-09 |
Synthesis of Adipic Acid by Clean Oxidation |
| |
| ZHANG Fu-li,YANG Shi-jing,ZHANG Meng.Synthesis of Adipic Acid by Clean Oxidation[J].Henan Chemical Industry,2006,23(11):15-16. |
| |
| Authors: | ZHANG Fu-li YANG Shi-jing ZHANG Meng |
| |
| Affiliation: | 1. Medical College of Henan University , Kaifeng 475001 , China ; 2. Kaifeng Kaihua (Group |
| |
| Abstract: | Using 30% of hydrogen peroxide as oxygen resource, sodium tungstate dehydrate as catalyst,KF - 101 as assist catalyst, adipic acid is synthesized by catalyzing and oxidizing cyclohexene. The influence of the amount of assist catalyst and catalyst, ratio of mole of reactors and reaction time on reaction are test, and optimum conditions via orthogonal test are found out. Under the optimum conditions, the yield of adipic acid reaches 93%. |
| |
| Keywords: | adipic acid cyclohexene hydrogen peroxide clean oxidation |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
