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Phase Disequilibrium in the Course of an Exothermic Reaction Accompanied by Liquid Evaporation in a Catalytic Trickle-Bed Reactor
Authors:Shigarov  A B  Kuzin  N A  Kirillov  V A
Affiliation:(1) Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. akademika Lavrent'eva 5, Novosibirsk, 630090, Russia
Abstract:agr-Methylstyrene hydrogenation in a fixed catalyst bed is studied experimentally and theoretically for a cocurrent downflow of the gas and liquid. Gas-phase hydrogenation on dry catalyst granules disturbs the liquid–vapor phase equilibrium. A dimensionless parameter related to the Raoult–Dalton law for a liquid–vapor mixture is suggested to characterize phase disequilibrium in the system.
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