1-甲基-4,5-二硝基咪唑包覆钝感CL-20研究 |
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引用本文: | 王小军,尚凤琴,王霞,鲁志艳,秦亮,杨学斌,苏强,杨彩云,曹端林.1-甲基-4,5-二硝基咪唑包覆钝感CL-20研究[J].四川兵工学报,2013,34(5):120-122. |
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作者姓名: | 王小军 尚凤琴 王霞 鲁志艳 秦亮 杨学斌 苏强 杨彩云 曹端林 |
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作者单位: | 1. 甘肃银光化学工业集团科研所,甘肃白银,730900 2. 中北大学化工与环境学院,太原,030051 |
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摘 要: | 利用1-甲基-4,5-二硝基咪唑(4,5-MDNI)在水中不同温度下的熔化和凝固结晶,通过水悬浮分散包覆工艺将4,5-MDNI包覆在六硝基六氮杂异伍兹烷(CL-20)颗粒的表面,制得外层为4,5-MDNI、内层为CL-20的双层混合炸药;采用扫描电镜观察了包覆前后炸药的显微结构、撞击感度测试表明:包覆后含量为6%的4,5-MDNI可使CL-20撞击感度(2.5 kg落锤)爆炸百分数由100%降低到8%;并通过DSC-TG技术研究了双层混合炸药的相容性。
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关 键 词: | 1-甲基-4 5-二硝基咪唑 六硝基六氮杂异伍兹烷 包覆 撞击感度 |
Study on Insensitivity CL-20 Coated with 4,5-MDNI |
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Authors: | WANG Xiao-jun SHANG Feng-qin WANG Xia LU Zhi-yan QIN Liang YANG Xue-bin SU Qiang YANG Cai-yun CAO Duan-lin |
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Affiliation: | 1.Research Institute of Gan Su Ying Guang Chemical Industry Group,Baiyin 730900,China; 2.College of Chemical Engineering and Environment,North University of China,Taiyuan 030051,China) |
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Abstract: | CL-20 was coated with a little 4,5-MDNI by melting,dispersion and cooling crystallization to CL-20 surface in water,a kind of double-deck composite explosive with low mechanical sensitivity,in which inside layer is CL-20 and outsider is 4,5-MDNI.Microscopic structures were analyzed by SEM with the variety of technical condition of coat.The impact sensitivity(2.5 kg)results show that the composite explosive reduce from 72% to 8% due to 6% of 4,5-MDNI coat.Compatibility of double layer composite explosive was studied by DSC-TG. |
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Keywords: | 1-Methl-4 5-nitroimidazole CL-20 coat impact sensitivity |
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